130409-58-4

Basic information

• Product Name: 2-allylcyclohex-1-en-1-yl acetate
• Synonyms: 2-allylcyclohex-1-en-1-yl acetate
• CAS NO: 130409-58-4
• Molecular Weight: 180.247
• Mol File: 130409-58-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-allylcyclohex-1-en-1-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-allylcyclohex-1-en-1-yl acetate(130409-58-4)
• EPA Substance Registry System: 2-allylcyclohex-1-en-1-yl acetate(130409-58-4)

Safety Data

• Hazardous Substances Data: 130409-58-4(Hazardous Substances Data)

Upstream product

• 41302-34-5 2-(methoxycarbonyl)cyclohexanone 
• 58648-11-6 methyl 2-allyl-2-cyclohexanonecarboxylate 
• 94-66-6 2-allylcyclohexan-1-one 
• 108-24-7 acetic anhydride 

Downstream Products

• 36302-35-9 (S)-2-allylcyclohexanone 
• 94-66-6 (R)-2-allylcyclohexanone 
• 1589528-89-1 (E)-2-(4-methyl-4-nitro-5-oxo-5-phenylpent-1-en-1-yl)cyclohex-1-en-1-yl acetate 
• 1322779-82-7 (E)-2-(4-nitro-5-oxo-5-phenylpent-1-en-1-yl)cyclohex-1-en-1-yl acetate 

Relevant articles and documents

Enzyme-mediated enantioface-differentiating hydrolysis of α-substituted cycloalkanone enol esters

A new type of enzymatic hydrolysis, enantioface-differentiating hydrolysis of enol esters, is disclosed. As a result of screening, Pichia miso IAM 4682, a type of yeast, was selected as the best strain to perform the enantioselective hydrolysis of enol esters to give α-chiral ketones. For example, incubation of 1-acetoxy-2-methylcyclohexene (4a) with P. miso afforded (S)-2-methylcyclohexanone (5) in high optical yield. This enzymatic hydrolysis is applicable to various α-substituted cycloalkanone enol esters, and thereby chiral six-, eight-, ten-, and twelve-membered-ring ketones of 70-96% enantiomeric excess (ee) are easily prepared.