1304513-75-4Relevant academic research and scientific papers
Iodoolefinic polypropionate building blocks from vinyl silanes with control of geometry by solvent and by neighboring group participation
Parker, Kathlyn A.,Denton, Richard W.
, p. 2115 - 2116 (2011/05/05)
Iododesilylation of trisubstituted (Z)-silyl olefins proceeds with retention of geometry in hexafluoroisopropanol (HFIP) but, for unhindered cases, with inversion of geometry in DMSO. When an acyloxy substituent is positioned to participate in the reactio
