1304540-30-4Relevant academic research and scientific papers
Addition of organometallic reagents to chiral N-methoxylactams: Enantioselective syntheses of pyrrolidines and piperidines
Jaekel, Mascha,Qu, Jianping,Schnitzer, Tobias,Helmchen, Guenter
, p. 16746 - 16755 (2014/01/06)
Enantioselective iridium-catalyzed allylic substitutions were used to prepare N-allyl hydroxamic acid derivatives that were suitable for ring-closing metathesis, giving N-methoxylactams. Reactions of these derivatives with Grignard or organolithium compou
Enantioselective iridium-catalyzed allylic substitutions with hydroxamic acid derivatives as N-nucleophiles
Gaertner, Martin,Jaekel, Mascha,Achatz, Manuel,Sonnenschein, Christoph,Tverskoy, Olena,Helmchen, Guenter
body text, p. 2810 - 2813 (2011/08/02)
Enantioselective Ir-catalyzed allylic aminations with hydroxamic acid derivatives are described. Catalysts were prepared in situ from [Ir(cod)Cl] 2 or [Ir(dbcot)Cl]2, a phosphoramidite and base. In addition, pure (φ-allyl)Ir complexe
