130467-35-5

Upstream product

• 498-15-7 (+)-Δ³-carene 
• 130467-34-4 (+)-cis-4-carboxymethyl-trans-carane 
• 131509-87-0 (+)-4-methylene-trans-carane 
• 130467-32-2 (+)-cis-4-formyl-trans-carene 
• 130467-31-1 (+)-trans-caran-cis-4-carbonitrile 
• 130467-33-3 (+)-trans-caran-cis-4-carboxylic acid 
• 4176-01-6 (-)-isocaranone 
• 4176-04-9 (1R,4S,6S)-4,7,7-Trimethyl-bicyclo[4.1.0]heptan-3-one 
• 4605-59-8 trans-4-Hydroxymethyl-2-carene 

Downstream Products

• 68804-32-0 (-)(1R,3R,4Ξ)-4,7,7-trimethyl-norcarane-3-carbaldehyde 

Relevant academic research and scientific papers

Synthesis of Some 4-Cyanocaranes

Four optically active 4-cyanocaranes diastereoisomers have been synthesized starting from (+)-car-3-ene and their structures supported by chemical evidences and X-ray analysis.

Synthesis of trans-Caran-4-carboxylic Acids

The synthesis of the optically active trans-caran-4-carboxylic acid 4a and 5a is reported.Methylene-cis and trans-caranes (8) and (9) were prepared by Wittig reaction from (-)-cis-caran-4-one (6).The structure of the described compounds are supported by chemical evidence.