1304685-34-4Relevant academic research and scientific papers
Copper-catalyzed direct amination of polyfluoroarenes and azoles with hydroxylamines and its application to the synthesis of 3-aminobenzoheteroles
Matsuda, Naoki,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
experimental part, p. 1792 - 1797 (2012/07/28)
A copper-catalyzed electrophilic, umpolung amination strategy for the direct C-H amination of polyfluoroarenes and 1,3-azoles has been developed. The copper-based amination reaction is robust and can be easily scaled up on a gram scale. Its application to
Copper-catalyzed direct amination of electron-deficient arenes with hydroxylamines
Matsuda, Naoki,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
supporting information; experimental part, p. 2860 - 2863 (2011/07/07)
The C-H amination of electron-deficient arenes such as polyfluoroarenes and azole compounds with O-acylated hydroxylamines effectively proceeds in the presence of a copper catalyst even at room temperature to provide the corresponding anilines and aminoaz
