1304695-93-9

Basic information

• Product Name: 4-methoxyphenyl (3,4-di-O-acetyl-2-O-benzyl-α-L-fucopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-N-phthalimido-β-D-glucopyranoside
• Synonyms: 4-methoxyphenyl (3,4-di-O-acetyl-2-O-benzyl-α-L-fucopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-N-phthalimido-β-D-glucopyranoside
• CAS NO: 1304695-93-9
• Molecular Weight: 823.851
• Mol File: 1304695-93-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-methoxyphenyl (3,4-di-O-acetyl-2-O-benzyl-α-L-fucopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-N-phthalimido-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxyphenyl (3,4-di-O-acetyl-2-O-benzyl-α-L-fucopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-N-phthalimido-β-D-glucopyranoside(1304695-93-9)
• EPA Substance Registry System: 4-methoxyphenyl (3,4-di-O-acetyl-2-O-benzyl-α-L-fucopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-N-phthalimido-β-D-glucopyranoside(1304695-93-9)

Safety Data

• Hazardous Substances Data: 1304695-93-9(Hazardous Substances Data)

Upstream product

• 1304695-84-8 C₁₉H₂₆O₆S 
• 138906-43-1 4-methoxyphenyl 4,6-di-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside 

Relevant articles and documents

Convergent synthesis of a common pentasaccharide corresponding to the O-antigen of Escherichia coli O168 and Shigella dysenteriae type 4

A convenient synthetic strategy of the common acidic pentasaccharide repeating unit corresponding to the O-antigen of enterotoxigenic E. coli O168 and Shigella dysenteriae type 4 has been successfully developed. A stereoselective [2+3] block glycosylation method has been exploited to get the target pentasaccharide derivative. Most of the synthetic intermediates were solid and prepared in high yields from commercially available reducing sugars following a series of protection-deprotection reactions. A α-D-mannose moiety has been used as the source of α-D-glucosamine moiety. A late-stage TEMPO mediated selective oxidation reaction finally resulted in the pentasaccharide containing a glucuronic acid unit.