130481-22-0Relevant academic research and scientific papers
Mise en evidence d'une reactivite specifique des trifluoromethylcetones vis-a-vis du bromure d'allylmagnesium
Felix, Caroline,Laurent, Andre,Mison, Pierre
, p. 71 - 82 (2007/10/02)
We wish to report on an unusual reactivity of allylmagnesium bromide.This Grignard reagent acts as a reducing agent towards trifluoromethylated ketones.A single electron transfer is suggested to explain the reductive process.By using an excess of allylmagnesium bromide, an exclusive addition reaction is obtained.The stereochemistry of both addition and reduction reactions is discussed. - Keywords: Trifluoromethyl ketones; Trifluoromethyl alcohols; Allylmagnesium bromide; Single electron transfer; Stereochemistry; NMR spectroscopy; IR spectroscopy; Mass spectrometry
Unusual reactivity of allylmagnesium bromide
Felix, Caroline,Laurent, Andre,Mison, Pierre
, p. 4143 - 4144 (2007/10/02)
Reaction of allylmagnesium bromide with trifluoromethyl oximes is different than with other Grignard reagents. On the other hand, allylmagnesium bromide acted as a reducing agent towards trifluoromethyl ketones. By using an excess of this Grignard reagent, an exclusive addition reaction is obtained. A single electron reaction is suggested to explain the reductive process.
