130484-15-0

Basic information

• Product Name: 3-bromo-1,1,1-trichloro-(3-cyclohexenyl)-propane
• Synonyms: 3-bromo-1,1,1-trichloro-(3-cyclohexenyl)-propane
• CAS NO: 130484-15-0
• Molecular Weight: 306.457
• Mol File: 130484-15-0.mol

Chemical Properties

• CAS DataBase Reference: 3-bromo-1,1,1-trichloro-(3-cyclohexenyl)-propane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-bromo-1,1,1-trichloro-(3-cyclohexenyl)-propane(130484-15-0)
• EPA Substance Registry System: 3-bromo-1,1,1-trichloro-(3-cyclohexenyl)-propane(130484-15-0)

Safety Data

• Hazardous Substances Data: 130484-15-0(Hazardous Substances Data)

Upstream product

• 75-62-7 Bromotrichloromethane 
• 100-40-3 4-ethenylcyclohexene 

Relevant articles and documents

The Fe0 promoted addition of CCl4 and CCl3Br to olefins

The radical addition of CCl4 or CCl3Br to olefins is efficiently promoted by iron filings in N,N-dimethylformamide under mild conditions.

ACTIVATION OF POLYHALOALKANES BY PALLADIUM CATALYST. FACILE ADDITION OF POLYHALOALKANES TO OLEFINS

Addition reaction of CCl4, CCl3Br, and CCl3CO2Me to olefins proceeded under mild conditions to afford 1 : 1 adduct in high yields by using palladium-phosphine complexes as a catalyst in the presence of bases.The reaction proceeded even at room temperature

Metal-free Photochemical Atom Transfer Radical Addition (ATRA) of BrCCl3 to Alkenes

A simple, photochemical, and metal-free protocol for the atom transfer radical addition (ATRA) of bromotrichloromethane onto various alkenes is described. Among a range of organic molecules, phenylglyoxylic acid proved to be the most suitable photoinitiator to promote a sustainable process for the addition of bromotrichloromethane to olefins. This photochemical atom transfer radical protocol can be expanded into a wide substrate scope of aliphatic olefins bearing various functional groups, leading to the corresponding products in good to excellent yields.

ADDITION OF POLYHALOGENO DERIVATIVES TO OLEFINS IN THE PRESENCE OF DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II) AND PROPYLAMAGNESIUM BROMIDE

Bromotrichloromethane and carbon tetrachloride add to monosubstituted and 2,2- and 1,2-disubstituted and trisubstituted olefins in the presence of the products from the reaction of nickel(II) complexes and alkylmagnesium halides.The trichloromethyl group is attached to the least substituted carbon atom of the double bond.

PALLADIUM-CATALYZED ADDITION REACTION OF POLYHALOALKANES TO OLEFINS

Pd(OAc)2 combined with phosphines catalyzes homolytic cleavage of the C-Cl bond of CCl4 and CCl3CO2CH3 leading to facile addition to olefins under mild conditions.BrCCl3 also reacts with olefins to give 1,1,1-trichloro-3-bromoalkanes.The reaction is accel