1305316-86-2Relevant academic research and scientific papers
Hybrid thiophosphoryl-benzothiazole palladium SCN-pincer complexes: Synthesis and effect of structure modifications on catalytic performance in the suzuki cross-coupling
Kozlov, Vladimir A.,Aleksanyan, Diana V.,Nelyubina, Yulia V.,Lyssenko, Konstantin A.,Petrovskii, Pavel V.,Vasil'ev, Andrei A.,Odinets, Irina L.
, p. 2920 - 2932 (2011/07/31)
The novel hybrid pincer-type ligands 3, 6, 9, and 11, bearing, as donating sites, a thiophosphoryl group and an imine moiety of the benzothiazole ring bound either directly to the central benzene core or attached to the latter one via O or NHlinkers, unde
Thiophosphoryl-, thiophosphoryloxy-, and thiophosphorylamino-benzene derivatives as novel classes of hybrid pincer ligands
Kozlov, Vladimir A.,Aleksanyan, Diana V.,Vasilev, Andrei A.,Odinets, Irina L.
, p. 626 - 637 (2011/06/22)
The synthetic approaches to novel families of SCE (E = S',N,O) hybrid pincertype ligands bearing thophosphoryl, thiophosphoryloxy, and thiophosphorylamino groups in various combinations with thiophosphoryl-, thiocarbamoyl-, and imine- (including that of benzothiazole ring) donating functions have been developed. All of the ligands readily undergo direct cyclometallation (metal = Pd(II), Pt(II)) to afford 5,5- or 5,6-membered pincer complexes. Palladium complexes displayed from high to excellent catalytic performance in the Suzuki cross-coupling reaction of aryl bromides and phenylboronic acid and the higher asymmetry for a complex served as a factor of its higher catalytic activity. Copyright Taylor & Francis Group, LLC.
