1305338-79-7Relevant academic research and scientific papers
Sulfoximine-directed single and double ortho-lithiation: Stereoselective rearrangements of o,oa'-Dilithiophenylsulfoximines to o,N- dilithiosulfinylanilines through anionic fries rearrangements of o,oa'-dilithiophenylsulfinamides
Wessels, Michael,Mahajan, Vishal,Bosshammer, Stephan,Raabe, Gerhard,Gais, Hans-Joachim
experimental part, p. 2431 - 2449 (2011/06/10)
Treatment of various phenylsulfoximines with nBuLi (1 equiv.) at -78 °C in THF resulted in single ortho-lithiations and gave the corresponding o-lithiosulfoximines. According to NMR spectroscopy, the o-lithiosulfoximines are generally stable at 0 °C. The
