1305338-87-7

Upstream product

• 1305338-61-7 (+)-(1S,6S)-6-(trimethylsilyl)methyl-1-phenyl-3,4,5,6-tetrahydro-1λ4-1,2-thiazine 1-oxide 
• 210552-40-2 (+)-(S)-1-Phenyl-3,4,5,6-tetrahydro[1,2]thiazin-1-oxide 

Relevant academic research and scientific papers

Sulfoximine-directed single and double ortho-lithiation: Stereoselective rearrangements of o,oa'-Dilithiophenylsulfoximines to o,N- dilithiosulfinylanilines through anionic fries rearrangements of o,oa'-dilithiophenylsulfinamides

Treatment of various phenylsulfoximines with nBuLi (1 equiv.) at -78 °C in THF resulted in single ortho-lithiations and gave the corresponding o-lithiosulfoximines. According to NMR spectroscopy, the o-lithiosulfoximines are generally stable at 0 °C. The