130534-80-4

Basic information

• Product Name: Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester
• Synonyms: Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester
• CAS NO: 130534-80-4
• Molecular Weight: 338.487
• Mol File: 130534-80-4.mol

Chemical Properties

• CAS DataBase Reference: Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester(130534-80-4)
• EPA Substance Registry System: Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester(130534-80-4)

Safety Data

• Hazardous Substances Data: 130534-80-4(Hazardous Substances Data)

Upstream product

• 1724-39-6 cyclododecanol 
• 42908-73-6 4-fluorophenyl chlorothionoformate 

Downstream Products

• 294-62-2 cyclododecane 

Relevant articles and documents

The invention of radical reactions. Part XXXI. Diphenylsilane: A reagent for deoxygenation of alcohols via their thiocarbonyl derivatives, deamination via isonitriles, and dehalogenation of bromo- and iodo- compounds by radical chain chemistry

Various thionocarbonates and xanthates of alcohols and bis-xanthates of vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins, while bromides and iodides are dehalogenated with diphenylphenylsilane in good yield.

The invention of radical reactions. Part XXIV. Relative rates of acylation and radical deoxygenation of secondary alcohols

Secondary alcohols were transformed into various thiocarbonyl derivatives. Reduction of these compounds using tributyltin hydride and an initiator afforded the corresponding deoxy-compounds. Half-life and competitive measurements showed that all these reactions were fast and could be run to completion.