130552-17-9Relevant articles and documents
Unified synthesis of vinylsilanes and silylated butadienes. Nickel-catalyzed olefination and silylolefination of dithioacetals
Ni, Zhi-Jie,Yang, Pin-Fan,Ng, Dennis K. P.,Tzeng, Yih-Ling,Luh, Tien-Yau
, p. 9356 - 9364 (2007/10/02)
A simple unified reaction has been developed in the syntheses of various vinylsilanes and silylated butadienes by the nickel-catalyzed coupling of dithioacetals with appropriate Grignard reagents. Reactions of 2-aryl-2-(trimethylsilyl)dithianes with MeMgI