130595-09-4Relevant academic research and scientific papers
Free radical cyclizations of terminal alkynes with oxime ethers
Enholm,Burroff,Jaramillo
, p. 3727 - 3730 (1990)
A benzyl oxime ether tethered to a terminal alkyne efficiently undergoes a free radical hydrostannylation reaction to afford five- and six-membered rings bearing a protected amine and a vinyl stannane functionally. These products were subsequently protiodestannylated to obtain the unsubstituted exo-methylene compounds.
