13061-96-6 Usage
Chemical Properties
White to light yellow crystal powde
Uses
Different sources of media describe the Uses of 13061-96-6 differently. You can refer to the following data:
1. suzuki reaction
2. Methylboronic Acid is a methylated derivative of boronic acid, a building block towards various intermediates in suzuki coupling.
3. Methylboronic acid can be used as a reagent:In the palladium-catalyzed Stille and Suzuki-Miyaura cross-couplings.In the microwave-heated heterogeneous palladium (Pd)-catalytized reactions.In ruthenium (Ru)-catalyzed silylation reactionsTo prepare bis(aminotropone) titanium (Ti) catalysts for ethylene polymerizations.In the enantioselective asymmetric bromoaminocyclization and bromoaminocyclization using amino-thiocarbamate catalysts.To prepare common building blocks for pharmaceuticals and agrochemicals.To prepare chrysin analogs by Suzuki-Miyaura coupling reactions.To prepare casein kinase I inhibitors.In the divergent C-H functionalizations directed by sulfonamide pharmacophores in drug discovery.In the synthesis of unsymmetrical monosulfides from disulfides via copper-catalyzed coupling with boronic acids.In a palladium-catalyzed coupling with enol tosylates.For derivatizing many carbohydrates and biologically active compounds for GLC analysis.
Check Digit Verification of cas no
The CAS Registry Mumber 13061-96-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,6 and 1 respectively; the second part has 2 digits, 9 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 13061-96:
(7*1)+(6*3)+(5*0)+(4*6)+(3*1)+(2*9)+(1*6)=76
76 % 10 = 6
So 13061-96-6 is a valid CAS Registry Number.
InChI:InChI=1/CH5BO2/c1-2(3)4/h3-4H,1H3
13061-96-6Relevant articles and documents
Koehler,Hess
, p. 5345,5346 (1974)
FUNCTIONALIZED PRIMARY ALKYLTRIFLUOROBORATE SALTS AND METHOD FOR MAKING THE SAME
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Paragraph 0100-0102, (2017/03/21)
The invention provides methods for preparing boronic acids, for example, primary alkyl or alkenyl boronic acids, and alkali metal alkyl trifluoro borate salts, as described herein, wherein the primary alkyl boronic acids and the potassium alkyl trifluoroborate salts can contain one or more unprotected functional groups.
Organoboranes. 39. Convenient procedures for the preparation of methylboronic acid and trimethylboroxin
Brown, Herbert C.,Cole, Thomas E.
, p. 816 - 821 (2008/10/08)
Methylboronic acid and its anhydride, trimethylboroxin, were prepared by three routes. The carbonylation of borane-dimethyl sulfide gives in high yields trimethylboroxin, readily hydrated to methylboronic acid. The reaction of methyllithium with selected
