130613-35-3Relevant articles and documents
A Stereospecific Synthesis of 3,3-Disubstituted Allylic Alcohols. The Intermolecular Pinacol Cross-Coupling Reaction between α,α-Disubstituted α-(Diphenylphosphinoyl)acetaldehydes (Ph2P(O)CR1R2CHO) and Saturated Aldehydes
Park, Jeonghan,Pedersen, Steven F.
, p. 5924 - 5926 (2007/10/02)
High diastereofacial selectivity is observed in the intermolecular pinacol cross-coupling of α,α-disubstituted α-(diphenylphosphinoyl)acetaldehydes with saturated aldehydes.The diols obtained from these reactions are converted to (E)-allylic alcohols via a Horner-Wittig elimination reaction.