130613-63-7Relevant academic research and scientific papers
Highly diastereoselective and enantiospecific allylation of ketones and imines using borinic esters: Contiguous quaternary stereogenic centers
Chen, Jack L.-Y.,Aggarwal, Varinder K.
supporting information, p. 10992 - 10996 (2015/03/30)
3,3-Disubstituted allylic boronic esters are not sufficiently reactive to react with ketones and imines. However they can be converted into the corresponding borinic esters by the sequential addition of nBuLi and TFAA. These reactive intermediates possess
A Stereospecific Synthesis of 3,3-Disubstituted Allylic Alcohols. The Intermolecular Pinacol Cross-Coupling Reaction between α,α-Disubstituted α-(Diphenylphosphinoyl)acetaldehydes (Ph2P(O)CR1R2CHO) and Saturated Aldehydes
Park, Jeonghan,Pedersen, Steven F.
, p. 5924 - 5926 (2007/10/02)
High diastereofacial selectivity is observed in the intermolecular pinacol cross-coupling of α,α-disubstituted α-(diphenylphosphinoyl)acetaldehydes with saturated aldehydes.The diols obtained from these reactions are converted to (E)-allylic alcohols via a Horner-Wittig elimination reaction.
