13063-61-1Relevant articles and documents
A Selective and General Cobalt-Catalyzed Hydroaminomethylation of Olefins to Amines
Beller, Matthias,Delolo, Fábio G.,Jackstell, Ralf,Spannenberg, Anke,Yang, Ji
supporting information, (2021/12/06)
A new cobalt catalyst is presented for the domino hydroformylation-reductive amination reaction of olefins. The optimal Co-tert-BuPy-Xantphos catalyst shows good to excellent linear-to-branched (n/iso) regioselectivity for the reactions of aliphatic alken
The electronic and steric effects of neutral and ionic phosphines on Ir(I)-complex catalyzed hydroaminomethylation of olefins
Liu, Huan,Yang, Da,Yao, Yixuan,Xu, Yongqiang,Shang, Hongyan,Lin, Xufeng
, (2020/02/26)
The electronic and steric effects of a series of neutral and ionic (mono-/di-)phosphines on the performance of Ir(I)-complex catalysts for the hydroaminomethylation of olefins were systematically investigated by means of 1J31P-7
Synthetic β-Cyclodextrin Dimers for Squaraine Binding: Effect of Host Architecture on Photophysical Properties, Aggregate Formation and Chemical Reactivity
Chaudhuri, Sauradip,Verderame, Molly,Mako, Teresa L.,Bandara, Y. M. Nuwan D. Y.,Fernando, Ashvin I.,Levine, Mindy
supporting information, p. 1964 - 1974 (2018/05/15)
Reported herein is the synthesis and application of three novel β-cyclodextrin dimer hosts for the complexation of near infrared (NIR) squaraine dyes in aqueous solution. A series of eight different N-substituted N-methyl anilino squaraine dyes with variable terminal groups are investigated, with an optimal n-hexyl-substituted squaraine guest demonstrating binding constants orders of magnitude higher than the other squaraine–host combinations and comparable to literature-reported systems. Moreover, hydrophobic complexation of the squaraine dyes with the β-cyclodextrin dimer hosts causes drastic changes in the squaraine's photophysical properties, propensity for aggregation and susceptibility to hydrolytic decay.