130659-98-2Relevant academic research and scientific papers
Stereoselective construction of three- and four-contiguous asymmetric centers: Novel possibility by alkylative rearrangement of epoxy silyl ethers
Shimazaki,Morimoto,Suzuki
, p. 3335 - 3338 (1990)
Stereospecific 1,2-rearrangement of epoxy silyl ethers in the presence of nucleophiles is described. The reaction affords 1,3-diols or corresponding mono-silylated ethers, which provides a route to establish three- or four-contiguous asymmetric centers in
