130660-06-9

Upstream product

• 108-24-7 acetic anhydride 
• 130659-94-8 2-Benzyloxymethyl-3-(2-trimethylsilanyl-1-triphenylsilanyloxy-allyl)-oxirane 
• 130660-00-3 (2R,3R,4R)-4-((R)-2-Benzyloxy-1-hydroxy-ethyl)-3-hydroxy-2-methyl-5-trimethylsilanyl-hex-5-enoic acid phenyl ester 
• 130660-01-4 (3R,4R,5R,6R)-6-Benzyloxymethyl-4-hydroxy-3-methyl-5-(1-trimethylsilanyl-vinyl)-tetrahydro-pyran-2-one 
• 130659-89-1 2-Benzyloxymethyl-3-(2-trimethylsilanyl-1-trimethylsilanyloxy-allyl)-oxirane 
• 130675-25-1 (2R,3S,4S,5S)-6-Benzyloxy-2-methyl-4-(1-trimethylsilanyl-vinyl)-hexane-1,3,5-triol 

Relevant academic research and scientific papers

Stereoselective construction of three- and four-contiguous asymmetric centers: Novel possibility by alkylative rearrangement of epoxy silyl ethers

Stereospecific 1,2-rearrangement of epoxy silyl ethers in the presence of nucleophiles is described. The reaction affords 1,3-diols or corresponding mono-silylated ethers, which provides a route to establish three- or four-contiguous asymmetric centers in