130663-45-5Relevant academic research and scientific papers
Chemically Efficient Aza-Di-?-Methane Photoreactivity with Novel Stable Derivatives of β,γ-Unsaturated Carbonyl Compounds
Armesto, Diego,Horspool, William M.,Mancheno, Maria J.,Ortiz, Maria J.
, p. 2325 - 2330 (2007/10/02)
The syntheses of new stable derivatives of β,γ-unsaturated carbonyl compounds such as 2,2-dimethyl-4,4-diphenylbut-3-enal 6 and 3,3-dimethyl-5,5-diphenylpent-4-en-2-one 7 are described.The majority of these derivatives undergo efficient aza-di-?-methane r
The Aza-di-?-methane Rearrangement of Stable Derivatives of 2,2-Dimethyl-4,4-diphenylbut-3-enal
Armesto, Diego,Horspool, William M.,Mancheno, Maria J.,Ortiz, Maria J.
, p. 2348 - 2349 (2007/10/02)
The sensitised irradiations of the semicarbazone (7a), the benzoylhydrazone (7b), and the oxime benzoate (7c) of 2,2-dimethyl-4,4-diphenylbut-3-enal afford the corresponding derivatives of 2,2-dimethylcyclopropanecarbaldehyde (8a-c) in good yield by an az
