13067-73-7Relevant academic research and scientific papers
Synthesis of cyclic phosphonate analogues of (lyso)phosphatidic acid using a ring-closing metathesis reaction
Zhang, Honglu,Tsukuhara, Ryoko,Tigyi, Gabor,Prestwich, Glenn D.
, p. 6061 - 6066 (2006)
We describe a versatile and efficient method for the preparation of acyloxy-substituted six-membered cyclic phosphonates using the ring-closing metathesis. After closure, the key cyclic phosphonate intermediate was dihydroxylated and converted to a new cl
NICKEL CHLORIDE CATALYZED REARRANGEMENT OF ALLYLIC PHOSPHITES
Lu, Xiyan,Zhu, Jingyang
, p. 239 - 244 (2007/10/02)
Allylic phosphites can be rearranged to the corresponding allylic phosphonates under the catalysis of nickel chloride.Dienes and dialkyl phosphonates are formed by an elimination reaction when there is hydrogen atom at the β-position of the carbon-metal bond in the allylic intermediate.The mechanisms of these reactions are discussed.
