130674-55-4Relevant academic research and scientific papers
Reactions of α-epoxysilanes with organocopper reagents. A stereoselective route to alkenes
Chauret, Denise C.,Chong, J. Michael
, p. 3695 - 3698 (2007/10/02)
Reactions of α-epoxysilanes with cuprate reagents can be controlled to give β-silyl alcohols as major products. An oxidation, Grignard addition, and elimination sequence then provides alkenes with up to 98% de.
GENERATION OF THIOALDEHYDES VIA FLUORIDE INDUCED ELIMINATION OF Α-SILYLDISULFIDES
Krafft, Grant A.,Meinke, Peter T.
, p. 1947 - 1950 (2007/10/02)
A mild, efficient and general method for the generation of reactive thioaldehydes from α-silyldisulfides is described.
