1306754-00-6

Upstream product

• 30752-19-3 1-bromo-4-hexyloxylbenzene 
• 39905-57-2 4-(n-hexyloxy)aniline 
• 1003-09-4 2-bromothiophene 
• 1158909-71-7 N,N-di(4-n-hexyloxyphenyl)amine 

Downstream Products

• 1393597-95-9 5-[N,N-bis(4-hexyloxyphenyl)amino]-2-(tri-n-butylstannyl)thiophene 
• 1393597-97-1 6-(5-(bis(4-(hexyloxy)phenyl)amino) thiophen-2-yl)-4,4-dihexyl-4H-cyclopenta[1,2-b:5,4-b']dithiophene-2-carbaldehyde 
• 1393597-99-3 (E)-3-(6-(5-(bis(4-(hexyloxy)phenyl)amino)thiophen-2-yl)-4,4-dihexyl-4H-cyclopenta[1,2-b:5,4-b']dithiophen-2-yl)-2-cyanoacrylic acid 
• 1393598-05-4 7-(5-(bis(4-(hexyloxy)phenyl)amino)thiophen-2-yl)-4,5-bis(hexyloxy)benzo[1,2-b:4,3-b']dithiophene-2-carbaldehyde 
• 1393598-08-7 (E)-3-(7-(5-(bis(4-(hexyloxy)phenyl)amino)thiophen-2-yl)-4,5-bis(hexyloxy)benzo[1,2-b:4,3-b']dithiophen-2-yl)-2-cyanoacrylic acid 
• 1306754-05-1 [5-(5-bromopyrimidin-2-yl)thiophen-2-yl]-N,N-bis(4-hexyloxyphenyl)amine 

Relevant academic research and scientific papers

NIR-Absorbing Dye Based on BF2-Bridged Azafulvene Dimer as a Strong Electron-Accepting Unit

BF2-bridged azafulvene dimers designed to be strong electron-accepting units were selectively synthesized using a bulky base. Single-crystal X-ray diffraction analysis revealed that the high electron-accepting ability of this structure stems from the contribution of the ?-conjugation mode of the azafulvene dimer upon formation of B-N coordination bonds. As a result of the low-lying LUMO energy of this electron-accepting unit, the corresponding D-A-D dye exhibits an intense NIR absorption band at 922 nm, which tails up to 1150 nm, while significant absorption bands in the visible region are absent. As a NIR dye this molecule exhibits moreover exceptional photostability and resistance to oxidation by atmospheric oxygen, even in dilute solution.

Push-pull type meso -ester substituted BODIPY near-infrared dyes as contrast agents for photoacoustic imaging

A series of push-pull type meso-ester substituted BODIPY dyes 1-4 with intense near-infrared absorption, largely enhanced photoacoustic (PA) activity and excellent photo-stability were synthesized. The impact of the electronic structure on the PA activity was also discussed. Moreover, the in vitro and in vivo PA imaging were investigated, which suggested a passive targeting capacity in the tumor site.