130695-53-3

Basic information

• Product Name: Bicyclo[2.2.1]heptane-2-thiol, 1,7,7-trimethyl-, (1S,2S,4S)-
• CAS NO: 130695-53-3
• Molecular Formula: C10H18S
• Molecular Weight: 170.319
• Mol File: 130695-53-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.1]heptane-2-thiol, 1,7,7-trimethyl-, (1S,2S,4S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptane-2-thiol, 1,7,7-trimethyl-, (1S,2S,4S)-(130695-53-3)
• EPA Substance Registry System: Bicyclo[2.2.1]heptane-2-thiol, 1,7,7-trimethyl-, (1S,2S,4S)-(130695-53-3)

Safety Data

• Hazardous Substances Data: 130695-53-3(Hazardous Substances Data)

Upstream product

• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 

Downstream Products

• 130592-83-5 (1S-exo)-2-bornyl 2,4-dinitrophenyl sulfide 
• 1416720-83-6 (1S,2S,4S,E)-N-(2-hydroxy-3,5-di-tert-butylbenzylidene)-1,7,7-trimethylbicyclo[2.2.1]-heptane-2-sulfenamide 
• 1416720-82-5 (1S,2S,4S,E)-N-(2-hydroxy-3,5-diiodobenzylidene)-1,7,7-trimethylbicyclo[2.2.1]heptane-2-sulfenamide 
• 1416721-07-7 (R)-(1S,2S,4S,E)-N-(4-dimethylaminobenzylidene)-1,7,7-trimethylbicyclo[2.2.1]heptane-2-sulfinamide 
• 1416721-06-6 (S)-(1S,2S,4S,E)-N-(4-dimethylaminobenzylidene)-1,7,7-trimethylbicyclo[2.2.1]heptane-2-sulfinamide 
• 1416720-81-4 (1S,2S,4S,E)-N-(2-hydroxy-3,5-dibromobenzylidene)-1,7,7-trimethylbicyclo[2.2.1]heptane-2-sulfenamide 
• 1416721-03-3 (R)-N-(E)-(2-hydroxy-5-dibromobenzylidene)-{(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfinamide 
• 1416721-01-1 (S)-N-(E)-(2-hydroxy-5-dibromobenzylidene)-{(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfinamide 
• 1416721-00-0 (R)-N-(E)-(2-hydroxy-5-chlorobenzylidene)-{(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfinamide 
• 1416720-98-3 (S)-N-(E)-(2-hydroxy-5-chlorobenzylidene)-{(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfinamide 
• 1416720-96-1 (R)-N-(E)-(2-hydroxy-3,5-di-tert-butylbenzylid-ene)-{(1S,2S,4S)-1,7,7-trimethylbicyclo-[2.2.1]heptane}-2-sulfinamide 
• 1416720-95-0 (S)-N-(E)-(2-hydroxy-3,5-di-tert-butylbenzylid-ene)-{(1S,2S,4S)-1,7,7-trimethylbicyclo-[2.2.1]heptane}-2-sulfinamide 
• 1416720-93-8 (R)-N-(E)-(2-hydroxy-3,5-diiodobenzylidene)-{(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfi namide 
• 1416720-92-7 (S)-N-(E)-(2-hydroxy-3,5-diiodobenzylidene)-{(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfi namide 

Relevant articles and documents

The Willgerodt-Kindler Reactions. 6. Isomerization of the Carbonyl Group in Alkanones and Cycloalkanones

The most unusual feature of the Willgerodt-Kindler Reactions is the facile isomerization of the carbonyl function along a chain of unbranched methylene groups, or around a cycloaliphatic ring containing several connected methylene groups.We have demonstrated that the first step in the Kindler process is the formation of enamines by reaction of the carbonyl function with secondary aliphatic amines, followed by reaction of the enamine with certain sulfur-amine catalysts to form reactive heterocyclic sulfur intermediates that facilitate the elimination-readdition of the amines reversibly along the chain.It was shown that compounds of the type R2N-S-S-NR2 are effective catalysts but not compounds of the type R2N-S-NR2.Some cyclohexanone derivatives undergo aromatization, with anomalous results in certain cases.