130714-20-4Relevant academic research and scientific papers
Synthesis of new perfluorotertiary amines containing geminal pentafluorosulfanyl, SF5, groups
Nielsen, Jon B.,Thrasher, Joseph S.
, p. 407 - 420 (1990)
The perfluorinated tertiary amines (SF5)2NCF3 [1], (SF5)2NC2F5, and (SF5)2NC3F7 have been prepared by the following scheme. Their overall yields were found to decrease markedly with respect to increases in the length of the perfluoro- {A figure is presented} alkyl chain. In fact, attempts to prepare (SF5)2NC4F9 have been unsuccessful thus far. The N-chloroamines were also reacted with simple olefins to give a variety of addition products such as SF5N(CF3)CH2CH2Cl, SF5N(CF3)CF2CF2Cl, SF5N(C2F5)CH2CH2Cl, and SF5N(C4F9)CH2CH2Cl.
