130746-45-1Relevant academic research and scientific papers
Palladium-catalyzed SN1 reactions of secondary benzylic alcohols: Etherification, amination, and thioetherification
Miller, Kimberly J.,Abu-Omar, Mahdi M.
, p. 1294 - 1299 (2003)
The reaction of various secondary benzylic alcohols in the presence of PdII catalysts provides ethers in good to high yields, Unsymmetric ethers could also be obtained with good selectivity by coupling two different alcohols. Direct amination is observed with electron-deficient anilines, and thioethers are prepared conveniently in high yields by the direct action of thiols on sec-phenylethyl alcohol. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
W-Ti-O mixed metal oxide catalyzed dehydrative cross-etherification of alcohols
Yada, Akira,Murayama, Toru,Hirata, Jun,Nakashima, Takuya,Tamura, Masanori,Kon, Yoshihiro,Ueda, Wataru
supporting information, p. 447 - 449 (2018/03/27)
A dehydrative cross-etherification reaction of two different alcohols is achieved in the presence of hydrothermally synthesized tungsten-titanium mixed metal oxide (W-Ti-O) catalyst. The reaction is environmentally benign: organic solvent is not necessary and the catalyst is readily recovered and reusable.
