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(1S,2S)-(-)-3-EXO-HYDROXY-2,10-CAMPHORSULTAM, also known as (-)-3-Exo-hydroxycamphor-10-sulphonamides, is a chiral sulphonamide compound with a camphor structure. It is commonly used as a chiral resolving agent in asymmetric synthesis, particularly in the resolution of racemic amines and alcohols. This chemical has been employed in various organic reactions and is known for its ability to selectively react with specific enantiomers to form diastereoisomeric sulphonamides, thereby facilitating the separation and purification of chiral molecules. Additionally, its camphor-based structure provides it with unique stereochemical properties, making it an important tool in the field of asymmetric synthesis and chiral separation.

130748-66-2

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130748-66-2 Usage

Uses

Used in Pharmaceutical Industry:
(1S,2S)-(-)-3-EXO-HYDROXY-2,10-CAMPHORSULTAM is used as a chiral resolving agent for the resolution of racemic amines and alcohols, which is crucial in the synthesis of enantiomerically pure pharmaceutical compounds. The ability to selectively react with specific enantiomers allows for the separation and purification of chiral molecules, ensuring the production of high-quality and effective drugs.
Used in Organic Chemistry Research:
In the field of organic chemistry, (1S,2S)-(-)-3-EXO-HYDROXY-2,10-CAMPHORSULTAM is used as a valuable tool for studying asymmetric synthesis and chiral separation techniques. Its unique stereochemical properties and camphor-based structure make it an important compound for understanding the behavior of chiral molecules in various organic reactions.

Check Digit Verification of cas no

The CAS Registry Mumber 130748-66-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,0,7,4 and 8 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 130748-66:
(8*1)+(7*3)+(6*0)+(5*7)+(4*4)+(3*8)+(2*6)+(1*6)=122
122 % 10 = 2
So 130748-66-2 is a valid CAS Registry Number.

130748-66-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name (1S,2S)-(-)-3-EXO-HYDROXY-2,10-CAMPHORSULTAM

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

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More Details:130748-66-2 SDS

130748-66-2Downstream Products

130748-66-2Relevant academic research and scientific papers

Asymmetric Diels-Alder Reaction of Cyclopentadiene and Methyl Acrylate catalysed by Chiral Lewis Acids

Ketter, Andreas,Glahsl, Gudrun,Herrmann, Rudolf

, p. 2118 - 2156 (2007/10/02)

The Diels-Alder reaction between cyclopentadiene and methyl acrylate under the influence of Lewis acids with aluminium, titanium, and tin as central metals and chiral chelating ligands has been studied under various conditions.True catalytic processes (with only 10 percent Lewis acid) have been found which lead to the cycloaddition product with diastereomeric ratio > 60 and enantiomeric excess up to 83 percent.The influence of the central metal, the ligand structure, the structure of the complexes, and the reaction conditions, on the results of the Diels-Alder reaction is discussed.The catalytically active species are probably 1:1 complexes, but dimers formed by ageing processes may also act as catalysts and lead to different diastereo- and enantioselectivities.

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