1307661-09-1Relevant articles and documents
Rh-catalyzed intramolecular debenzylative cyclization of amines. Butyrolactams from benzylamines having a chloroacetylene moiety
Oh, Yun Taek,Senda, Kousuke,Hata, Takeshi,Urabe, Hirokazu
experimental part, p. 2458 - 2461 (2011/05/16)
When benzylamines having a chloroacetylene moiety were heated in wet toluene with a catalytic amount of rhodium trifluoroacetate dimer, intramolecular debenzylative cyclization took place to give butyrolactams. This method is a new entry to selective debenzylation of amines.