13080-79-0

Upstream product

• 1458-98-6 2-methyl-3-bromo-1-propene 
• 131-57-7 Benzophenone-3 

Downstream Products

• 134617-19-9 (Z)-9-Methoxy-3-methyl-6-phenyl-4H,6H-benzo[b][1,5]oxathiocine 
• 121150-41-2 2-Isopropyl-6-methoxy-3-phenyl-2,3-dihydro-benzofuran 
• 121150-40-1 1-Benzyl-4-methoxy-2-(2-methyl-propenyloxy)-benzene 
• 121150-37-6 [4-Methoxy-2-(2-methyl-allyloxy)-phenyl]-phenyl-methanethione 

Relevant academic research and scientific papers

Palladium-catalyzed cascade cyclization of allylamine-tethered alkylidenecyclopropanes: Facile access to iodine/difluoromethylene- and perfluoroalkyl-containing 1-benzazepine scaffolds

The unprecedented palladium-catalyzed cascade cyclization of allylamine-tethered alkylidenecyclopropanes with an ethyl difluoroiodoacetate or perfluoroalkylated reagent is developed, providing facile access to a variety of synthetically and medicinally valuable iodine/difluoromethylene- and perfluoroalkyl-containing 1-benzazepine frameworks. These reactions exhibited good yields and functional group tolerance via a radical mechanism.

INTRAMOLECULAR ENE REACTION ON UNSATURATED THIOKETONES

The thermal cyclization of o-(2-substituted allyloxy)thiobenzophenones giving 1,5-oxathiocine derivatives is reported.This is the first example of the new type intramolecular ene reaction of unsaturated thioketones.