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  • 5-Norbornen-2-ol CAS 13080-90-5 Bicyclo[2.2.1]hept-5-en-2-ol CAS no 13080-90-5 3,6-ENDOMETHYLENE-1,2,3,6-TETRAHYDROPHENOL

    Cas No: 13080-90-5

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13080-90-5 Usage

Uses

It is applied in High Performance Liquid Chromatography. (HPLC) and Nuclear Magnetic Resonance (NMR).

Check Digit Verification of cas no

The CAS Registry Mumber 13080-90-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,8 and 0 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 13080-90:
(7*1)+(6*3)+(5*0)+(4*8)+(3*0)+(2*9)+(1*0)=75
75 % 10 = 5
So 13080-90-5 is a valid CAS Registry Number.
InChI:InChI=1/C7H10O/c8-7-4-5-1-2-6(7)3-5/h1-2,5-8H,3-4H2

13080-90-5 Well-known Company Product Price

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  • Alfa Aesar

  • (H56994)  5-Norbornen-2-ol, mixture of endo and exo, 99%   

  • 13080-90-5

  • 1g

  • 206.0CNY

  • Detail
  • Alfa Aesar

  • (H56994)  5-Norbornen-2-ol, mixture of endo and exo, 99%   

  • 13080-90-5

  • 25g

  • 3541.0CNY

  • Detail
  • Aldrich

  • (N32105)  5-Norbornen-2-ol,mixtureofendoandexo  99%

  • 13080-90-5

  • N32105-5G

  • 1,125.54CNY

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  • Aldrich

  • (N32105)  5-Norbornen-2-ol,mixtureofendoandexo  99%

  • 13080-90-5

  • N32105-25G

  • 3,866.85CNY

  • Detail

13080-90-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 5-Norbornene-2-OL,mixture of endo and exo

1.2 Other means of identification

Product number -
Other names bicyclo[2.2.1]hept-5-en-2-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13080-90-5 SDS

13080-90-5Relevant articles and documents

Stereoselective [4+2]-Cycloaddition with Chiral Alkenylboranes

Brown, M. Kevin,Houk, K. N.,Ni, Dongshun,Witherspoon, Brittany P.,Zhang, Hong,Zhou, Chen

supporting information, p. 11432 - 11439 (2020/05/18)

A method for the stereoselective [4+2]-cycloaddition of alkenylboranes and dienes is presented. This transformation was accomplished through the introduction of a new strategy that involves the use of chiral N-protonated alkenyl oxazaborolidines as dieneophiles. The reaction leads to the formation of products that can be readily derivatized to more complex structural motifs through stereospecific transformations of the C?B bond such as oxidation and homologation. Detailed computation evaluation of the reaction has uncovered a surprising role of the counterion on stereoselectivity.

α-Hydroxyacids accelerate the Diels-Alder reaction of dibutyl vinylboronate with cyclopentadiene: Experimental results and mechanistic insights

Grimblat,Sarotti,Pisano,Pellegrinet

, p. 1966 - 1969 (2016/03/22)

We have found that α-hydroxyacids accelerate the Diels-Alder reaction of dibutyl vinylboronate with cyclopentadiene. When stoichiometric quantities are used, excellent yields are obtained, while catalytic activities are moderate. DFT calculations suggested that the activation of the dienophile occurs by ligand exchange with both functionalities of the α-hydroxyacid.

A facile microwave-assisted Diels-Alder reaction of vinylboronates

Sarotti, Ariel M.,Pisano, Pablo L.,Pellegrinet, Silvina C.

supporting information; experimental part, p. 5069 - 5073 (2010/12/25)

The Diels-Alder reaction of vinylboronates can be easily performed using microwave irradiation giving excellent yields of the cycloadducts. Pinacol vinylboronate was the reagent of choice due to its stability towards hydrolysis, operational simplicity and yields of Diels-Alder products. To the best of our knowledge, this is the first example of microwave-assisted Diels-Alder reaction of boron-substituted dienophiles. Subsequent in situ oxidation of the cycloadducts with alkaline hydrogen peroxide afforded the alcohols efficiently.

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