1308271-84-2Relevant academic research and scientific papers
Total synthesis and absolute stereochemistry of (+)-batzellaside B and its C8-epimer, a new class of piperidine alkaloids from the sponge batzella sp.
Wierzejska, Jolanta,Ohshima, Manami,Inuzuka, Toshiyasu,Sengoku, Tetsuya,Takahashi, Masaki,Yoda, Hidemi
, p. 1173 - 1175 (2011/03/21)
The first total synthesis of (+)-batzellaside B and its C8-epimer was completed from a known l-arabinose-derived tribenzyl ether in 22 steps with overall yields of 3.9% and 5.4%, respectively. The absolute configuration of (+)-batzellaside B was unambiguously determined to be 1S,3S,4S,5R,8S by the Mosher analysis of a synthetic intermediate prepared through a separate route.
