130829-45-7Relevant academic research and scientific papers
Template-directed synthesis of linear and cyclic butadiyne-linked porphyrin oligomers up to a linear octamer
Anderson, Sally,Anderson, Harry L.,Sanders, Jeremy K. M.
, p. 2247 - 2254 (2007/10/02)
Efficient syntheses of a cyclic porphyrin dimer, cyclic trimer, cyclic tetramer, linear dimer, linear tetramer, and linear octamer are described.Starting from a zinc porphyrin monomer, simple oligopyridine ligands are used as templates to control oligomerisation by binding to the linear intermediates formed under Glaser-Hay coupling conditions.The oligomeric products have been characterised using FAB, high-resolution electrospray and MALDITOF mass spectrometry.
Enzyme mimics based on cyclic porphyrin oligomers: strategy, design and exploratory synthesis
Anderson, Harry L.,Sanders, Jeremy K. M.
, p. 2223 - 2230 (2007/10/02)
A strategy is set out for the design and synthesis of a series of cyclic porphyrin oligomers which should be able to bind two or more substrate molecules, catalyse a reaction between them and release the product(s).Exploratory syntheses and some spectrosc
