1308324-56-2

Upstream product

• 81028-12-8 (4S,5R)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-5-carboxaldehyde 
• 143878-62-0 (4S,5S)-4-[(benzyloxy)methyl]-2,2-dimethyl-5-vinyl-1,3-dioxolane 

Downstream Products

• 1308324-61-9 C₂₅H₃₈O₉ 
• 1308324-58-4 (1S)-1-{(4S,5S)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl}ethan-1-ol 
• 1308324-59-5 (4S,5S)-4-[(benzyloxy)methyl]-5-[(1S)-1-(methoxymethoxy)ethyl]-2,2-dimethyl-1,3-dioxolane 
• 1308324-62-0 (4R)-6-[(4-methoxybenzyl)oxy]-4-(methoxymethoxy)-1-{(4R,5S)-5-[(1S)-1-(methoxymethoxy)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}-2-hexyn-1-one 
• 1308324-63-1 (1S,4R)-6-[(4-methoxybenzyl)oxy]-4-(methoxymethoxy)-1-{(4S,5S)-5-[(1S)-1-(methoxymethoxy)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}-2-hexyn-1-ol 
• 1308324-49-3 (4S,5S)-4-[(1S,4R)-6-[(4-Methoxybenzyl)oxy]-1,4-di(methoxymethoxy)-2-hexynyl]-5-[(1S)-1-(methoxymethoxy)ethyl]-2,2-dimethyl-1,3-dioxolane 
• 1308324-57-3 C₂₂H₂₈O₇S 

Relevant academic research and scientific papers

Stereoselective total synthesis of the cytotoxic lactone (-)-spicigerolide

A highly stereoselective synthesis of the naturally occurring lactone (-)-spicigerolide has been achieved utilizing OsO4-catalyzed dihydroxylation, CBS, Lindlar's reductions, Still-Gennari, and Grignard reactions as the key reaction steps.