130837-84-2Relevant academic research and scientific papers
Enhanced catalytic activity in asymmetric hydrosilylation of 1,3-dienes with a soluble palladium catalyst
Han, Jin Wook,Hayashi, Tamio
, p. 325 - 331 (2007/10/03)
A new MOP ligand 8 containing two n-octyl groups at the 6 and 6′ positions of the (R)-2-(diphenylphosphino)-2′-aryl-1,1′-binaphthyl skeleton was prepared and used for the palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes with trichlorosilane. T
Catalytic Asymmetric Hydrosilylation of 1,3-Dienes with New Chiral Ferrocenylphosphine-Palladium Complexes
Hayashi, Tamio,Matsumoto, Yonetatsu,Morikawa, Ikutaro,Ito, Yoshihiko
, p. 151 - 154 (2007/10/02)
A palladium catalyst coordinated with optically active ferrocenylmonophosphine ligand containing perfluoroalkyl group on the aminoethyl side chain was found to be highly catalytically active and stereoselective for the asymmetric hydrosilylation of several types of conjugated dienes with trichlorosilane to give optically active allylsilanes of over 60percent ee.
