13086-65-2Relevant academic research and scientific papers
Oxygen Exchange and Cleavage of the Glycinate Chelate 2+ in Strongly Alkaline Solution
Buckingham, David A.,Clark, Charles R.
, p. 133 - 138 (2007/10/02)
Cleavage of the carboxylate chelate 2+ has been studied in 0.75 mol dm-3 NaOH. 18O-tracer results are interpreted as 16percent C-O and 84percent Co-O bond fission, the products ultimately being +, Co(II), and glyO-.The major Co-O cleavage path is interpreted as an SN1 (CB) process leading to both recapture of carboxylate oxygen(50percent, kex=4.8 * 10-6 s-1) and capture of solvent leading to + (50percent).
