1308650-68-1Relevant academic research and scientific papers
Mild and selective H/D exchange at the β position of aromatic α-olefins by N-heterocyclic carbene-hydride-rhodium catalysts
Di Giuseppe, Andrea,Castarlenas, Ricardo,Perez-Torrente, Jesus J.,Lahoz, Fernando J.,Polo, Victor,Oro, Luis A.
, p. 3938 - 3942 (2011)
Pacman bites selectively! Stable rhodium(III)-N-heterocyclic carbene-hydride complexes (Pacman-like catalysts) are highly active and selective catalysts for H/D exchange at the β position of aromatic α-olefins (see picture). The interplay between bulky N-
