1308732-57-1

Basic information

• Product Name: ETHYL 2-(1-ALLYL-2-OXO-1,2-DIHYDRO-3H-INDOL-3-YLIDEN)ACETATE
• Synonyms: ETHYL 2-(1-ALLYL-2-OXO-1,2-DIHYDRO-3H-INDOL-3-YLIDEN)ACETATE
• CAS NO: 1308732-57-1
• Molecular Formula: C₁₅H₁₅NO₃
• Molecular Weight: 257.28
• Mol File: 1308732-57-1.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ETHYL 2-(1-ALLYL-2-OXO-1,2-DIHYDRO-3H-INDOL-3-YLIDEN)ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 2-(1-ALLYL-2-OXO-1,2-DIHYDRO-3H-INDOL-3-YLIDEN)ACETATE(1308732-57-1)
• EPA Substance Registry System: ETHYL 2-(1-ALLYL-2-OXO-1,2-DIHYDRO-3H-INDOL-3-YLIDEN)ACETATE(1308732-57-1)

Safety Data

• Hazardous Substances Data: 1308732-57-1(Hazardous Substances Data)

Upstream product

• 924-44-7 glyoxylic acid ethyl ester 
• 91-56-5 indole-2,3-dione 
• 830-74-0 1-allyl-1H-indole-2,3-dione 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 1450989-35-1 C₃₁H₂₇N₃O₄S 

Relevant articles and documents

A Morita–Baylis–Hillman Pathway to Wittig Products: One-Pot Transformation of Nitroalkylideneoxindoles to Oxindolylidene-Carboxylates

An unusual Morita–Baylis–Hillman (MBH) type reactivity of isatin-derived nitroalkenes with activated carbonyl compounds has been demonstrated for the first time. The unexpected 3-alkylideneoxindole esters were formed in moderate to excellent yields with complete stereoselectivity (only E-isomer). The proposed mechanism based on control experiments involves a hybrid MBH–Wittig pathway.

Chemoselective reduction of isatin-derived electron-deficient alkenes using alkylphosphanes as reduction reagents

Under mild reaction conditions, the C=C double bond inisatin-derived electron-deficient alkenes has been exclusively reduced in the presence of alkylphosphanes and water to afford the corresponding reduction products in good to excellent yields. A plausib