130878-30-7

Basic information

• Product Name: 4-Hydroxy-3-methoxycinnamaldehyde, trimethylsilyl derivative
• Synonyms: 4-Hydroxy-3-methoxycinnamaldehyde, trimethylsilyl derivative
• CAS NO: 130878-30-7
• Molecular Formula: C₁₃H₁₈O₃Si
• Molecular Weight: 250.37
• Mol File: 130878-30-7.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 335.9±37.0 °C(Predicted)
• Appearance: /
• Density: 1.024±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 4-Hydroxy-3-methoxycinnamaldehyde, trimethylsilyl derivative(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Hydroxy-3-methoxycinnamaldehyde, trimethylsilyl derivative(130878-30-7)
• EPA Substance Registry System: 4-Hydroxy-3-methoxycinnamaldehyde, trimethylsilyl derivative(130878-30-7)

Safety Data

• Hazardous Substances Data: 130878-30-7(Hazardous Substances Data)

Usage

InChI:InChI=1S/C13H18O3Si/c1-15-13-10-11(6-5-9-14)7-8-12(13)16-17(2,3)4/h5-10H,1-4H3/b6-5+

Upstream product

• 458-36-6 trans-coniferyl aldehyde 
• 25561-30-2 N,O-Bis(trimethylsilyl)trifluoroacetamide 

Relevant articles and documents

Reactivity of ferulic acid and its derivatives toward hydrogen peroxide and peracetic acid

The reactions of ferulic acid and its derivatives with hydrogen peroxide and peracetic acid in lignin-retaining bleaching conditions have been investigated to determine their susceptibility to oxidative degradation. The conjugated side chain of ferulic acid and its etherified or esterified derivative was shown to be fairly stable, especially to hydrogen peroxide. The major reaction was trans-cis isomerization that possibly involved a radical mechanism but did not cause bond cleavage. The peracetic acid reaction increased the rate of trans-cis isomerization and was also accompanied by a minor cleavage of the side chain. Esterification did not have a substantial effect on the reactivity of ferulic acid, but 4-O- etherification significantly stabilized it against these two oxidants. By contrast, aldehyde substitution tremendously enhanced the susceptibility of the cinnamyl side chain to oxidative degradation, as evidenced by an intensive degradation of coniferaldehyde.