13088-34-1Relevant articles and documents
Synthetic Approaches to Chlorinated 5-Hydroxy-5-Methyl-2-Furanones
Franzen, Robert,Kronberg, Leif
, p. 10945 - 10958 (2007/10/02)
The syntheses of chlorinated 5-hydroxy-furanones with a mono-, di-, and trichloromethyl group at C-5 are described.The 5-chloromethyl hydroxyfuranones were obtained by chlorination of levulinic acid followed by triethylamine promoted elimination of hydrogen chloride.Hydrolyses of chlorinated 4-cyclopentene-1,3-diones yielded 5-dichloromethyl hydroxyfuranones.The trichloromethyl group was incorporated to maleic anhydride through thermal decomposition of sodium trichloroacetate.