130894-39-2Relevant academic research and scientific papers
MeOTf-induced carboannulation of arylnitriles and aromatic alkynes: A new metal-free strategy to construct indenones
Yan, Xiaoyu,Zou, Song,Zhao, Peng,Xi, Chanjuan
supporting information, p. 2775 - 2777 (2014/03/21)
MeOTf-induced carboannulation of arylnitriles and aromatic alkynes for synthesis of indenones under metal-free conditions has been described. When ortho-substituted benzonitriles were used, indeno[1,2-c]isoquinolines were formed.
A deuterium labelling study into the insertion of diphenylacetylenes into iron-aryl bonds
Butler, Ian R.,Elliot, Joanne L.,Houde, Jean
, p. 1564 - 1573 (2007/10/02)
The mechanism of the reaction of dicarbonyl(η5-cyclopentadienyl)phenyliron, 1, with diphenylacetylene to give 2,3-diphenyl--inden-1-one has been investigated using a partially deuterated 1.The mechanistic pathway of the reaction is discussed in terms of the labelling of the indenones obtained.The reaction of phenylacetylene with 1 gives a mixture of products including 2,4,6-triphenyl-4'-methylbenzophenone and C-4,C-6a-dihydro-4-(4'-methylphenyl)-2-phenylpentalene(1-r-3aH)one.
