13091-06-0

Upstream product

• 3449-26-1 1,1,3,3-tetramethyl-1,3-diphenyldisilazane 
• 62-53-3 aniline 
• 768-33-2 phenyldimethylsilyl chloride 
• 766-77-8 Dimethylphenylsilane 
• 1125-26-4 dimethylphenylvinylsilane 

Downstream Products

• 24004-65-7 N-(dimethyl(phenyl)silyl)-1,1-dimethyl-N,1-diphenylsilanamine 
• 13722-27-5 N-Dimethylphenylsilyl-N,N'-diphenylharnstoff 

Relevant academic research and scientific papers

Palladium nanoparticles supported on graphene as catalysts for the dehydrogenative coupling of hydrosilanes and amines

Palladium nanoparticles (Pd NPs) were supported on undoped and N- or B-doped graphenes (Gs) and these materials have been used as catalysts for the dehydrogenative coupling of hydrosilanes and amines to form silazanes. Working under optimal conditions, a conversion over 99% and a selectivity of 84% were achieved for the reaction of dimethylphenylsilane with morpholine. In contrast, copper (Cu NPs) or nickel nanoparticles (Ni NPs) supported on G did not promote the formation of the corresponding Si-N coupling product. It was found that Pd/G performed better for this coupling than analogous catalysts, in which Pd NPs were supported on active carbon, multiwall carbon nanotubes or diamond NPs. Pd/G as a catalyst has a wide substrate scope, including aliphatic and aromatic amines and mono or dihydrosilanes. Pd/G undergoes a gradual deactivation due to the growth and partial agglomeration of Pd NPs and the aggregation of G sheets, as observed by TEM. This journal is

Indirect Nuclear Spin-Spin Coupling Constants of Nitrogen-15 to Silicon-29 in Silylamines

The 15N-29Si spin-spin coupling constants in silylamines have been measured from 29Si satellites in their natural abundance 15N n.m.r. spectra in an INEPT sequence for accumulation of signals and interpreted in terms of Fermi-contact interaction; the sensitivity of 1J(15N-29Si) to d?-p? bonding was noted.

Highly efficient dehydrogenative coupling of hydrosilanes with amines or amides using supported gold nanoparticles

Hydroxyapatite-supported gold nanoparticles (Au/HAP) can act as a highly active and reusable catalyst for the coupling of hydrosilanes with amines under mild conditions. Various silylamines can be selectively obtained from diverse combinations of equimola

Ruthenium-catalyzed dealkenative N-silylation of amines by substituted vinylsilanes

The ruthenium hydride complex-catalyzed N-silylation of primary and secondary amines with substituted vinylsilanes, with the general formula R1CHCHSiR′3 (where R1 = H, Ph, n-Bu, Si(OEt)3), leading to the formation of a Si-

Catalytic dehydrogenative Si-N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base

A base-free, catalytic protocol for the dehydrogenative Si-N coupling of weakly nucleophilic N-H groups of heteroarenes or aryl-substituted amines with equimolar amounts of hydrosilanes is reported. Cooperative Si-H bond activation at a Ru-S bond generates a silicon electrophile that forms a Si-N bond prior to the N-H deprotonation by an intermediate Ru-H complex, only releasing H 2. The Royal Society of Chemistry 2013.

Cationic silane δ-complexes of ruthenium with relevance to catalysis

Hydrosilylation of carbonyls catalyzed by 2 goes via intermediate formation of cationic silane σ-complexes 4 which undergo nucleophilic abstraction of the silylium cation studied by DFT calculations.