13091-06-0

Basic information

• Product Name: Silanamine, 1,1-dimethyl-N,1-diphenyl-
• CAS NO: 13091-06-0
• Molecular Formula: C14H17NSi
• Molecular Weight: 227.381
• Mol File: 13091-06-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Silanamine, 1,1-dimethyl-N,1-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, 1,1-dimethyl-N,1-diphenyl-(13091-06-0)
• EPA Substance Registry System: Silanamine, 1,1-dimethyl-N,1-diphenyl-(13091-06-0)

Safety Data

• Hazardous Substances Data: 13091-06-0(Hazardous Substances Data)

Upstream product

• 3449-26-1 1,1,3,3-tetramethyl-1,3-diphenyldisilazane 
• 766-77-8 Dimethylphenylsilane 
• 62-53-3 aniline 
• 1125-26-4 dimethylphenylvinylsilane 
• 768-33-2 phenyldimethylsilyl chloride 

Downstream Products

• 13722-27-5 N-Dimethylphenylsilyl-N,N'-diphenylharnstoff 
• 24004-65-7 N-(dimethyl(phenyl)silyl)-1,1-dimethyl-N,1-diphenylsilanamine 

Relevant articles and documents

Palladium nanoparticles supported on graphene as catalysts for the dehydrogenative coupling of hydrosilanes and amines

Palladium nanoparticles (Pd NPs) were supported on undoped and N- or B-doped graphenes (Gs) and these materials have been used as catalysts for the dehydrogenative coupling of hydrosilanes and amines to form silazanes. Working under optimal conditions, a conversion over 99% and a selectivity of 84% were achieved for the reaction of dimethylphenylsilane with morpholine. In contrast, copper (Cu NPs) or nickel nanoparticles (Ni NPs) supported on G did not promote the formation of the corresponding Si-N coupling product. It was found that Pd/G performed better for this coupling than analogous catalysts, in which Pd NPs were supported on active carbon, multiwall carbon nanotubes or diamond NPs. Pd/G as a catalyst has a wide substrate scope, including aliphatic and aromatic amines and mono or dihydrosilanes. Pd/G undergoes a gradual deactivation due to the growth and partial agglomeration of Pd NPs and the aggregation of G sheets, as observed by TEM. This journal is

Highly efficient dehydrogenative coupling of hydrosilanes with amines or amides using supported gold nanoparticles

Hydroxyapatite-supported gold nanoparticles (Au/HAP) can act as a highly active and reusable catalyst for the coupling of hydrosilanes with amines under mild conditions. Various silylamines can be selectively obtained from diverse combinations of equimola

Catalytic dehydrogenative Si-N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base

A base-free, catalytic protocol for the dehydrogenative Si-N coupling of weakly nucleophilic N-H groups of heteroarenes or aryl-substituted amines with equimolar amounts of hydrosilanes is reported. Cooperative Si-H bond activation at a Ru-S bond generates a silicon electrophile that forms a Si-N bond prior to the N-H deprotonation by an intermediate Ru-H complex, only releasing H 2. The Royal Society of Chemistry 2013.