130914-24-8 Usage
Uses
Chlorodicyclopentylphosphine may be used to prepare:Cp,Cp-MannOP, a chiral diphosphinite ligand by reacting with mannitol.[Cp=cyclopentyl; Mann=mannitol](S)-Cp,Cp-oxoProNOP, a bis(dicycloalkylphosphino) amidophosphine-phosphinite ligand by reacting with (S)-5-(hydroxymethyl)-2-pyrrolidinoneLcPeNiCl, a precursor for preparing LcPeNiH, which is an efficient catalyst for the reduction of CO2[cPe=cyclopentyl]
General Description
Chlorodicyclopentylphosphine is a phosphine precursor for ligand preparation in Negishi and Suzuki coupling reactions.
Check Digit Verification of cas no
The CAS Registry Mumber 130914-24-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,0,9,1 and 4 respectively; the second part has 2 digits, 2 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 130914-24:
(8*1)+(7*3)+(6*0)+(5*9)+(4*1)+(3*4)+(2*2)+(1*4)=98
98 % 10 = 8
So 130914-24-8 is a valid CAS Registry Number.
InChI:InChI=1/C10H18ClP/c11-12(9-5-1-2-6-9)10-7-3-4-8-10/h9-10H,1-8H2
130914-24-8Relevant articles and documents
2,2'-bis (dicyclopentylphosphino)-1,1'-binaphthyl and transition metal complex using the same as ligand
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, (2008/06/13)
Novel 2,2'-bis(dicyclopentylphosphino)-1,1'-binaphthyl represented by formula (I): STR1 and a transition metal complex using the same as a ligand, are disclosed. The transition metal complex is industrially excellent as a catalyst for various asymmetric synthesis reactions.
