1309356-75-9Relevant academic research and scientific papers
Different modes of cyclization in zoanthamine alkaloid system, bisaminal versus spiroketal formation
Nakajima, Takahiro,Yamashita, Daisuke,Suzuki, Kaname,Nakazaki, Atsuo,Suzuki, Takahiro,Kobayashi, Susumu
supporting information; experimental part, p. 2980 - 2983 (2011/08/05)
Bisaminal cyclization in the zoanthamine alkaloid system was strongly affected by the stereochemistry of the C4 methyl. While cyclization of the (4S)-methyl precursor gave only a bisaminal compound, cyclization of the (4R)-methyl isomer produced both spiroketal and bisaminal products.
