1309458-19-2

Upstream product

• 1309458-13-6 (R)-5-(benzo[d][1,3]dioxol-5-yl)cyclohex-2-enone 
• 1309458-14-7 (5R)-5-(benzo[d][1,3]dioxol-5-yl)cyclohex-2-enol 
• 1309458-16-9 (1S,4S,6R)-6-(benzo[d][1,3]dioxol-5-yl)-4-(triisopropylsiloxy)cyclohex-2-enol 
• 1309458-17-0 (1S,4S,6R)-6-(benzo[d] [1,3]dioxol-5-yl)-4-(triisopropylsiloxy)cyclohex-2-enyl ethyl carbonate 
• 1309458-18-1 ((1S,4S,5R)-4-azido-5-(benzo[d][1,3]dioxol-5-yl)cyclohex-2-enyloxy)triisopropylsilane 
• 541-41-3 chloroformic acid ethyl ester 
• 1309458-15-8 (1S,4S,5R)-5-(benzo[d][1,3]dioxol-5-yl)cyclohex-2-ene-1,4-diol 
• 1309458-11-4 (S)-5-(cyclohexa-2,4-dienyl)benzo[d][1,3]dioxole 
• 1019840-66-4 (1E,4E)-1-(benzo[d][1,3]dioxol-5-yl)deca-1,4-dien-3-one 

Downstream Products

• 1309458-41-0 ethyl (1R,2S,3S,4S,6R)-6-(benzo[d][1,3]dioxol-5-yl)-2,3-dihydroxy-4-(triisopropylsilyloxy)cyclohexylcarbamate 
• 1309458-20-5 (1S,2S,3R,4R,6S)-4-(benzo[d][1,3]dioxol-5-yl)-3-(ethoxycarbonylamino)-6-(triisopropylsilyloxy)cyclohexane-1,2-diyl diethanoate 

Relevant academic research and scientific papers

A boron-based synthesis of the natural product (+)-trans- dihydrolycoricidine

Diastereoselective diboration results in the highly selective 1,4-dihydroxylation of chiral cyclohexadienes (see scheme). Together with the catalytic enantioselective conjugate allylboration, the diene diboration facilitates the asymmetric synthesis of the cytotoxic agent (+)-trans- dihydrolycoricidine (1). pin=pinacol. Copyright