1309466-74-7

Basic information

• Product Name: (E)-(3-methylbut-1-ene-1,4-diyl)dibenzene
• Synonyms: (E)-(3-methylbut-1-ene-1,4-diyl)dibenzene
• CAS NO: 1309466-74-7
• Molecular Weight: 222.33
• Mol File: 1309466-74-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-(3-methylbut-1-ene-1,4-diyl)dibenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(3-methylbut-1-ene-1,4-diyl)dibenzene(1309466-74-7)
• EPA Substance Registry System: (E)-(3-methylbut-1-ene-1,4-diyl)dibenzene(1309466-74-7)

Safety Data

• Hazardous Substances Data: 1309466-74-7(Hazardous Substances Data)

Upstream product

• 140-10-3 (E)-3-phenylacrylic acid 
• 2114-39-8 (2-bromopropyl)-benzene 
• 1227853-34-0 C₁₆H₂₅O₃PS 
• 1589-82-8 phenylmagnesium bromide 
• 17488-65-2 4-phenylbut-3-en-2-ol 

Relevant articles and documents

Oxidative Addition to Palladium(0) Made Easy through Photoexcited-State Metal Catalysis: Experiment and Computation

Visible-light induced, palladium catalyzed alkylations of α,β-unsaturated acids with unactivated alkyl bromides are described. A variety of primary, secondary, and tertiary alkyl bromides are activated by the photoexcited palladium metal catalyst to provide a series of olefins at room temperature under mild reaction conditions. Mechanistic investigations and density functional theory (DFT) studies suggest that a photoinduced inner-sphere mechanism is operative in which a barrierless, single-electron transfer oxidative addition of the alkyl halide to Pd0 is key for the efficient transformation.