130979-47-4Relevant academic research and scientific papers
Diels-Alder Reactions of Sulfur-Substituted Allenecarboxylates: An FMO Approach by the PM3-Method
Conrads, Martin,Mattay, Jochen
, p. 867 - 873 (2007/10/02)
The effect of captodative (c,d) substitution of some olefins and allenes has been investigated by MNDO-PM3 calculations.These results are compared with the Diels-Alder reactions of α-sulfur-substituted allenecarboxylates. α-Sulfonyl allenecarboxylates 6 are a new class of stable gem-diacceptor-substituted allenes.
