1309881-90-0Relevant articles and documents
Rhodium-catalyzed asymmetric formal olefination or cycloaddition: 1,3-dicarbonyl compounds reacting with 1,6-diynes or 1,6-enynes
Suda, Takeshi,Noguchi, Keiichi,Tanaka, Ken
, p. 4475 - 4479 (2011/06/25)
A cationic rhodium(I) complex catalyzes the title reaction of 1,6-diynes through a [2+2+2] cycloaddition and subsequent electrocyclic ring opening (see scheme; cod=1,5-cyclooctadiene, H8-binap=2,2′- bis(diphenylphosphino)-5,5′,6,6′,7,7′,8,8′-octahydro-1, 1′-binaphthyl). The asymmetric intramolecular [2+2+2] cycloaddition of 1,3-dicarbonyl compounds with 1,6-enynes was also accomplished. Copyright