1309962-34-2

Upstream product

• 118629-75-7 (S)-2-hydroxypent-4-en-1-yl 4-methylbenzenesulfonate 
• 70987-78-9 (S)-Glycidyl tosylate 
• 1309962-33-1 ethyl (2-(hydroxymethyl)allyl) carbonate 

Downstream Products

• 1309962-35-3 C₂₅H₃₈O₉SSi 
• 1309962-44-4 C₂₇H₄₂O₉SSi 

Relevant academic research and scientific papers

Enantioselective total synthesis of a natural iridoid

The first total synthesis of 6-hydroxy-7-(hydroxymethyl)-4- methylenehexahydrocyclopenta[c]pyran-1(3H)-one has been accomplished. A key feature of the synthesis includes facile construction of the bicyclic lactone intermediate via intramolecular Pd(0)-catalyzed allylic alkylation and the efficient transformation of this intermediate into the iridoid skeleton employing silicon tethered radical cyclization.