131035-87-5Relevant academic research and scientific papers
Allylsulfone in free radical reaction
Chuang,Hou,Wu
, p. 467 - 476 (2007/10/02)
A sulfonyl radical induced addition-cyclization reaction of vinylcyclopropane and 1,6-diene by using allylsulfone as sulfonyl radical precursor to give functionalized cyclopentane is described.
SULPHONYL RADICAL ADDITION TO NON-CONJUGATED DIENES. REGIO- AND STEREOSELECTIVE CYCLIZATIONS
Riggi, I. De,Surzur, J.-M.,Bertrand, M. P.,Archavlis, A.,Faure, R.
, p. 5285 - 5294 (2007/10/02)
Addition of TsBr to diallyl malonates and allyl methallyl malonates is described.These cyclization reactions exhibit high stereoselectivity and very high regioselectivity.The structure of the reaction products is elucidated using 2D NMR.
